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Chemistry 6 Online
OpenStudy (anonymous):

How do you convert methan to acetic acid?

OpenStudy (anonymous):

The conversion of methane to acetic acid is currently carried out in a three-step process Methane is first reformed in a heterogeneously catalyzed process that is energy- and capitalintensive to produce synthesis gas, a mixture of CO and H2. The CO and H2 then react at high pressure in a second step to produce methanol, and finally, in the third step, acetic acid is produced by homogeneous-phase carbonylation of methanol. Because of the strong demand for acetic acid (3.1 million tons/year by the plastics, textiles, paper, paints, and adhesives industries, there is considerable interest in finding ways to synthesize acetic acid directly from methane. Sevaral studies have recently shown how this might be done. For example, methane will undergo oxidative carbonylation in either water or strong acid catalyzed by Rh or Cu cations, and the carboxylation of methane has been demonstrated in both water and strong acids using soluble V-based catalysts . A particularly interesting approach for the direct synthesis of acetic acid from methane who describe the oxidation of methane to acetic acid catalyzed by Pd2+ cations in 96 wt% sulfuric acid. The only other products observed are methyl bisulfate (a precursor to methanol) and carbon dioxide. Whereas the selectivity to the liquid-phase products is reported to be as high at 90%, Pd2+ is observed to precipitate from solution as Pd-black, causing the reaction to stop. In some case reproduces these observations and showed that the addition of Cu2+ and O2 to the reaction mixture enhances the yield of acetic acid without dramatically increasing the yield of methyl bisulfate or decreasing the selectivity. The aim of the present study was to investigate the effects of CH4 and O2 partial pressure, temperature, and sulfuric acid concentration on the synthesis of acetic acid and on the retention of Pd2+ in solution. The pathways leading to the formation of CO and CO2 were examined, as was the mechanism by which the carboxylate group in CH3COOH is formed. A further aim of this study was to identify the effects of reaction conditions on the formation of sulfur-containing acids, such as methanesulfonic acid, methane disulfonic acid, and sulfoacetic acid

OpenStudy (anonymous):

this should help :)

OpenStudy (anonymous):

I wanted equations but thanks anyway :)

OpenStudy (anonymous):

oh srry ur welcome

OpenStudy (sreekar369):

CH4+CO2-->CH3COOH

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