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Chemistry 8 Online
OpenStudy (bloomlocke367):

How do I balance this redox equation using the oxidation-number-change method?

OpenStudy (bloomlocke367):

@justuu @dan815

OpenStudy (bloomlocke367):

\(HCl(aq)+Zn(s)->ZnCl_2(s)+H_2(g)\)

OpenStudy (bloomlocke367):

@Preetha

OpenStudy (bloomlocke367):

@TheSmartOne @zepdrix

OpenStudy (bloomlocke367):

@Joel_the_boss

OpenStudy (jfraser):

split the reaction into its two half-reactions

OpenStudy (bloomlocke367):

Yay, you're back on!

OpenStudy (jfraser):

zinc gets oxidized, and the hydrogen ion gets reduced

OpenStudy (bloomlocke367):

How do I do that?

OpenStudy (jfraser):

Do you see how the zinc starts with a charge of zero and ends with a charge of +2?

OpenStudy (bloomlocke367):

Yes

OpenStudy (jfraser):

so the half-reaction for the zinc is\[Zn^0 \rightarrow Zn^{+2} + 2e^{-1}\]

OpenStudy (bloomlocke367):

How/Why?

OpenStudy (jfraser):

because the only way for a zinc to form a +2 charge from a zero charge is to lose 2 electrons

OpenStudy (bloomlocke367):

oh, okay.

OpenStudy (jfraser):

what happens to the \(hydrogen\) in the reaction?

OpenStudy (bloomlocke367):

it starts with +1, correct?

OpenStudy (jfraser):

it does, and how does it end as a product?

OpenStudy (bloomlocke367):

to be honest, I'm not sure...

OpenStudy (jfraser):

when it's bonded to itself, a diatomic molecule like hydrogen has a charge of zero

OpenStudy (bloomlocke367):

Oh, okay.

OpenStudy (jfraser):

so does \(O_2\), \(N_2\), and all monatomic solids like \(Zn\), \(Fe\), and \(C\) all have charges of zero

OpenStudy (jfraser):

since the hydrogen starts as +1 and ends as a 0, what is its half-reaction?

OpenStudy (bloomlocke367):

\(H^{1+}+e^{-1} ->H^0\)?

OpenStudy (jfraser):

close, but the product is still \(H_2\), so you need more than 1 \(H^{+1}\) ion

OpenStudy (jfraser):

\[2H^{+1} + 2e^{-1} \rightarrow H_2\]

OpenStudy (bloomlocke367):

Oh, okay.

OpenStudy (bloomlocke367):

so how does this balance it?

OpenStudy (jfraser):

each half-reaction is separate, but if you add them together, like you could add 2 algebraic equations together, watch what happens

OpenStudy (bloomlocke367):

and it's balanced?

OpenStudy (jfraser):

it is, and see how one half-reaction produce 2 electrons, and the other half-reaction uses 2 electrons as a reactant?

OpenStudy (jfraser):

so the electrons cancel on both sides because they're like terms\[Zn^0 + 2H^{+1} + \cancel{2e^{-1}} \rightarrow Zn^{+2} + H_2 + \cancel{2e^{-1}}\]

OpenStudy (bloomlocke367):

Oh, wow, thank you! it actually makes sense now.

OpenStudy (jfraser):

YW

OpenStudy (bloomlocke367):

Do you think you might be able to help me more if I need it? I don't think I will.

OpenStudy (jfraser):

if i'm available, i'll see what i can do

OpenStudy (jfraser):

all redox reactions can get balanced this way, you split the reaction into its two halfs, balance each half separately, then add them back together

OpenStudy (bloomlocke367):

Thank you so much! I used to love chem...and now.. not so much XD and okay, thank you

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