need help with basic thermochemistry. PLEASE HELP
I got -485.6 kJ for #3
@aaronq
that's right, i posted that calculation in the previous thread - you must've missed it
yea u did, I just didnt go back
I'm doing 4 and I'm lost @aaronq there is more products in the equations than I need for the target equation
Calculate ∆H for the reaction CH4 (g) + NH3 (g) \(\rightarrow\) HCN (g) + 3 H2 (g), from the reactions. 1. N2 (g) + 3 H2 (g) \(\rightarrow\) 2 NH3 (g) ∆H = –91.8 kJ 2. C (s, graphite) + 2 H2 (g) \(\rightarrow\) CH4 (g) ∆H = –74.9 kJ/mol 3. H2 (g) + 2 C (s, graphite) + N2 (g) \(\rightarrow\) 2 HCN (g) ∆H = +270.3 kJ to 1.: divide by 2 and reverse to 2.: reverse to 3.: divide by 2 1. NH3 (g) \(\rightarrow\) 1/2 N2 (g) + 3/2 H2 (g) 2. CH4 (g) \(\rightarrow\) C (s, graphite) + 2 H2 (g) 3. 1/2 H2 (g) + C (s, graphite) + 1/2 N2 (g) \(\rightarrow\) HCN (g) 1.∆H =(1/2)*(+270.3) kJ 2.∆H = 74.9 kJ/mol 3. ∆H =(1/2)*91.8 kJ
1. NH3 (g) → 1/2 N2 (g) + \(\cancel{1/2 H2 (g)}\)+ 2/2 H2 (g) 2. CH4 (g) → C (s, graphite) + 2 H2 (g) 3. \(\cancel{1/2 H2 (g)}\) + C (s, graphite) + 1/2 N2 (g) → HCN (g) etc
hmm
doubts?
yea trying to figure it out on paper
okay cool
for 2, why isnt the C(s) cancelled out? @aaronq
it should be, i just didn't do all of them to keep things focused. the 1/2 N2 and the C should be cancelled
ok
@sweetburger I have a quick question
thers like 4 on that pdf which one @Anikate
5
Im wondering if I have to flip any equations in that question
You have to reverse the last one for sure.
and I think you have to multiply the last one by 2 but im not sure yet
I think you mulitply the 3rd by 3 and the 2nd by 6
1. nothing 2. multiply by 6 3. multiply by 3 4. reverse and mutlipyl by2 let me check this to see if it works
sorry my computer shut off. im back
ya so the steps i listed should be correct that will allow you to find the enthalpy change
if you have to reverse 4 dont u also have to reverse 2?
no I dont think so?
why would 2 have to be reversed?
because HCl is in the equation
just like AlCL3 is in the equation
@sweetburger
Ok so if you reverse 4 your changing which side the solid and gaseous version of AlCl3 is. This doesnt affect what happens to #2 reaction. Literally apply that changes the i told you to do and then cancel out and see what is left.
oh ok do I only reverse an equation if one of its reactants is suppsoed to be a product?
is that true @sweetburger
@Anikate Im almost certain
sweet i have to take an online chem quiz on thermo basics, can you pleas help me?
its 25 questions
timed 40 mins
you there? @sweetburger
are you busy right now?
bro Im busy right now I dont want to say i can be here and help and have you rely on me if I have to go
oh ok, so can you help? imma need instand replies just double my work and answer questions
@mathstudent55
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