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Chemistry 13 Online
OpenStudy (anonymous):

1. Determine the volume of sodium hydroxide added to the flask from the buret. 2. Calculate the molarity of the Hydrochloric acid in the flask. Information: Initial volume of NaOH in buret: 0 mL Volume of HCI in flask: 20 mL pH when 0 mL of NaOH has been added: 0.70 Volume of NaOH remaining at end point: 30 mL pH each time 5 mL of NaOH is added: (amount in mL|pH: 5 mL|0.96 pH 10 mL|1.3 pH 15 mL|2.15 pH 20 mL|7.00 pH (now neutral) 25 mL|12.7 pH 30 mL|12.85 pH 35 mL|12.94 pH 40 mL|13 pH 45 mL|13.05 pH 50 mL|13.08 pH Thanks so much!!

OpenStudy (anonymous):

@nincompoop @ikram002p @oldrin.bataku @TheAsker2002 @BloomLocke367 @dmndlife24 @rvc @JoannaBlackwelder

OpenStudy (joannablackwelder):

I am guessing what it is looking for in the first question is, how much sodium hydroxide is added to the flask to get to the equivalence point (which for strong acids mixed with strong bases is a pH of 7)

OpenStudy (joannablackwelder):

Does that make sense, @lovelylolita55 ?

OpenStudy (anonymous):

Yes, you are correct @JoannaBlackwelder

OpenStudy (anonymous):

Sorry I took forever to reply @JoannaBlackwelder

OpenStudy (joannablackwelder):

No worries. So, how much volume is NaOH is that?

OpenStudy (anonymous):

30 mL?

OpenStudy (joannablackwelder):

Hm, it looks like to me the data shows it is a pH of 7 at 20 mL added.

OpenStudy (anonymous):

Oh that's what you meant. Yes, pH of 7 at 20 mL.

OpenStudy (joannablackwelder):

:-) And for the next part, do you have the molarity of NaOH and the balanced reaction?

OpenStudy (anonymous):

Yes, the buret was filled with 0.25 molar NaOH solution.

OpenStudy (joannablackwelder):

Nice, and the reaction?

OpenStudy (anonymous):

I'm not sure I have that info..This was a strong acid - strong base neutralization reaction between NaOH and HCI

OpenStudy (anonymous):

Is that what you're asking for? :P

OpenStudy (joannablackwelder):

Yep, do you know the general form of a neutralization reaction?

OpenStudy (anonymous):

No, I don't think I do

OpenStudy (joannablackwelder):

All strong acid/strong base reactions form water and a salt

OpenStudy (anonymous):

Oh I see

OpenStudy (anonymous):

So the molarity of the HCI would be? I don't know how to calculate that

OpenStudy (joannablackwelder):

Well, when we write the reaction: HCl+NaOH->H2O+NaCl

OpenStudy (joannablackwelder):

We have a balanced reaction already, since the number of each element is the same on each side.

OpenStudy (joannablackwelder):

So that means we have a 1:1 molar ratio of HCl and NaOH

OpenStudy (anonymous):

Ok

OpenStudy (joannablackwelder):

We can then use the molarity of the NaOH and the volume to find how many moles of NaOH were needed in the reaction.

OpenStudy (joannablackwelder):

Can you do that step?

OpenStudy (anonymous):

So concentration and volume?

OpenStudy (joannablackwelder):

Yep

OpenStudy (anonymous):

So the volume of HCI would be 20 mL, but I'm not sure about the molarity.

OpenStudy (joannablackwelder):

We have both for NaOH though.

OpenStudy (joannablackwelder):

We are looking for the molarity of HCl

OpenStudy (anonymous):

Oh I see, so they would be equal? Since the ratio is 1:1

OpenStudy (joannablackwelder):

The number of moles are equal.

OpenStudy (anonymous):

ok

OpenStudy (anonymous):

Hmm I'm having a bit of trouble remembering how to do this :'(

OpenStudy (joannablackwelder):

So, the molarity formula is Molarity=mols solute/L solution

OpenStudy (joannablackwelder):

Can you use that to calculate moles of NaOH?

OpenStudy (anonymous):

0.0125...is that terribly wrong? lol

OpenStudy (joannablackwelder):

Hm, how did you get that?

OpenStudy (anonymous):

M = 0.25 mols / 20 mL...I messed that up, didn't I?

OpenStudy (joannablackwelder):

Yeah, the .25 isn't the moles it is the M (molarity)

OpenStudy (joannablackwelder):

And the molarity formula requires the volume to be in L, so we need to convert mL->L

OpenStudy (anonymous):

Oh i see

OpenStudy (joannablackwelder):

:-)

OpenStudy (anonymous):

0.02 L then?

OpenStudy (joannablackwelder):

Yep

OpenStudy (anonymous):

I'm not sure what the amount of moles are then

OpenStudy (joannablackwelder):

Well, the formula with what we know plugged in is: .25=moles NaOH/.02

OpenStudy (joannablackwelder):

Do you see how I substituted?

OpenStudy (anonymous):

Yes, that's brilliant lol

OpenStudy (joannablackwelder):

:D haha, thanks! Can you solve for moles?

OpenStudy (anonymous):

I just got another out of wack number..could you maybe walk me through that one too? You're helping me out so much!

OpenStudy (joannablackwelder):

What number did you get? And I'm glad i can help. :-)

OpenStudy (anonymous):

12.5..but that didn't seem right?

OpenStudy (joannablackwelder):

Yeah, I did it this way:|dw:1432312836260:dw| where x stands for moles of NaOH

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