Another question: Going to post them in a bit.
Will post soon. Going to be on the rate constant, and kinetics.
Posted here other one got cut off
Some more here
=D
Ok I think this is the last one for this question
I know this is a lot but some of them aren't that bad.
@Rushwr @taramgrant0543664
Ill start with the easy one 276. Im pretty sure OH is a intermediate
276. it's gotta be an intermediate because if it were a catalyist it would be generated in the last step again and unchanged. (Promoter and activator make no sense)
For 275 I'm not sure but I think that the concentration of CaCl2 would have no affect on the rate because it is a product and it isnt affecting the forward reaction. Not sure if my reasoning on this is sound though.
My answer also came down to that for 275 B,C, and D. would change the rate of the reaction.
Yea actually im certain for 275 that A would be the only answer that would not affect the reaction rate.
Yeah, sounds right to me, I guess the concentration of \(CaCl_2\) would only affect the equilibrium constant.
wait... I don't know for some reason I can't really decide between A and B
289. which one is false? A. Chlorine goes from an oxidation state of 0 to -1 so it's reduced so that's true B. increasing the temperature generally does increase the rate of reaction. \[k = Ae ^{Ea/Rt}\] you increase temperature i think the quantitiy Ea/Rt goes down i believe and k goes up and reaction rate goes up as well. D yes HCL is a strong acid, and HCLO is a weak acid so that's true.
289 I think is C.
289. is C. here's my justification
The only thing that affect the equilibrium constant is temperature from what I remember.
Yeah it shouldn't affect the equilibrium constant, I guess the rate constant is not affected by concentrations of the products only concentration of reactants.
Like i thought it was C for 289 b/c I notice that the number of moles of each quantity are the same. To me like an increase in pressure favors the side with fewer number of moles i think , while a decrease in pressure favors the side with more moles.. Keq
yeah it's only affected by temperature as well
sorry.. i was thinking in terms of what would favor the products.
My answer choice for 290 is B.
Okay so 276 D. "An OH radical is formed in the rate determining step but is consumed in the next step therefore it's an intermediate" 289 C The equilibrium constant is not affected by changes in concentrations and pressures remember that equilibrium states are separate from kinetic studies.
Looks good.
Yeah for 289 I don't think partial pressures come into play because we're only talking about liquids.
290. \[k[cl _{2}]^{0.5}[H _{2}O]\]
IF you look at the slow step the rate for formation depends on the formation of the chlorine radical and it's ability to react with water as well.
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