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Chemistry 21 Online
OpenStudy (photon336):

Another question: Going to post them in a bit.

OpenStudy (photon336):

Will post soon. Going to be on the rate constant, and kinetics.

OpenStudy (photon336):

Posted here other one got cut off

OpenStudy (photon336):

Some more here

OpenStudy (photon336):

=D

OpenStudy (photon336):

Ok I think this is the last one for this question

OpenStudy (photon336):

I know this is a lot but some of them aren't that bad.

OpenStudy (photon336):

@Rushwr @taramgrant0543664

OpenStudy (sweetburger):

Ill start with the easy one 276. Im pretty sure OH is a intermediate

OpenStudy (photon336):

276. it's gotta be an intermediate because if it were a catalyist it would be generated in the last step again and unchanged. (Promoter and activator make no sense)

OpenStudy (sweetburger):

For 275 I'm not sure but I think that the concentration of CaCl2 would have no affect on the rate because it is a product and it isnt affecting the forward reaction. Not sure if my reasoning on this is sound though.

OpenStudy (sweetburger):

My answer also came down to that for 275 B,C, and D. would change the rate of the reaction.

OpenStudy (sweetburger):

Yea actually im certain for 275 that A would be the only answer that would not affect the reaction rate.

OpenStudy (anonymous):

Yeah, sounds right to me, I guess the concentration of \(CaCl_2\) would only affect the equilibrium constant.

OpenStudy (anonymous):

wait... I don't know for some reason I can't really decide between A and B

OpenStudy (photon336):

289. which one is false? A. Chlorine goes from an oxidation state of 0 to -1 so it's reduced so that's true B. increasing the temperature generally does increase the rate of reaction. \[k = Ae ^{Ea/Rt}\] you increase temperature i think the quantitiy Ea/Rt goes down i believe and k goes up and reaction rate goes up as well. D yes HCL is a strong acid, and HCLO is a weak acid so that's true.

OpenStudy (sweetburger):

289 I think is C.

OpenStudy (photon336):

289. is C. here's my justification

OpenStudy (sweetburger):

The only thing that affect the equilibrium constant is temperature from what I remember.

OpenStudy (anonymous):

Yeah it shouldn't affect the equilibrium constant, I guess the rate constant is not affected by concentrations of the products only concentration of reactants.

OpenStudy (photon336):

Like i thought it was C for 289 b/c I notice that the number of moles of each quantity are the same. To me like an increase in pressure favors the side with fewer number of moles i think , while a decrease in pressure favors the side with more moles.. Keq

OpenStudy (photon336):

yeah it's only affected by temperature as well

OpenStudy (photon336):

sorry.. i was thinking in terms of what would favor the products.

OpenStudy (sweetburger):

My answer choice for 290 is B.

OpenStudy (photon336):

Okay so 276 D. "An OH radical is formed in the rate determining step but is consumed in the next step therefore it's an intermediate" 289 C The equilibrium constant is not affected by changes in concentrations and pressures remember that equilibrium states are separate from kinetic studies.

OpenStudy (sweetburger):

Looks good.

OpenStudy (anonymous):

Yeah for 289 I don't think partial pressures come into play because we're only talking about liquids.

OpenStudy (photon336):

290. \[k[cl _{2}]^{0.5}[H _{2}O]\]

OpenStudy (photon336):

IF you look at the slow step the rate for formation depends on the formation of the chlorine radical and it's ability to react with water as well.

OpenStudy (photon336):

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