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Chemistry 13 Online
OpenStudy (photon336):

Which of the following is the chief factor leading to why the density of ice less than the density of water?

OpenStudy (photon336):

A. Hydrogen bonding. B. Formation of covalent bonds between water molecules. C. the energy change when water freezes. D. the lower entropy of the solid.

OpenStudy (taramgrant0543664):

It would be due to the hydrogen bonding

OpenStudy (photon336):

I'm pretty sure that the energy change when water freezes would not have any affect on the density

OpenStudy (photon336):

\[\Delta S \] probably wouldn't affect the density either..

OpenStudy (photon336):

Tara I think i agree with you

OpenStudy (rushwr):

I agree tooo !!!!!!!!!

OpenStudy (taramgrant0543664):

Its due to hydrogen bonding dominating the intermolecular forces, which results in a packing of molecules less compact in the solid.

OpenStudy (photon336):

ok here is explanation: "A water exhibits hydrogen bonding between molecules. when water begins to freeze a crystal structure is formed using those h bonds, in this crystal structure there are large empty spaces that make the density less".

OpenStudy (photon336):

like I chose A because the others made no sense

OpenStudy (photon336):

as water freezes (l)-->(s).. hydrogen bonding ceases?

OpenStudy (photon336):

Formation of covalent bonds makes no sense because that implies that there aren't any in water, and there are, H bonding is a type of covalent bonding.

OpenStudy (taramgrant0543664):

hydrogen bonds causes molecules to push farther apart, which lowers the density.

OpenStudy (anonymous):

whats the confusion ?

OpenStudy (photon336):

ok I see. since they are farther apart, density is less. that makes sense.

OpenStudy (anonymous):

the molecules have less energy and hydrogen bonding takes over. The molecules form a ordered crystal through hydrogen bonding that spaces the molecules farther apart than when they were in a liquid. This makes ice less dense than water

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