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If you had 1 mole of CaSO4x2H2O, how many moles of H2O would you have?
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You can see that every unit of CaSO4x2H2O contains TWO molecules of H2O, so for however much CaSO4x2H2O you have, there will be twice as much H2O. If there's 1 mole of CaSO4x2H2O, there are 2 moles of H2O.
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