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Chemistry 22 Online
OpenStudy (anonymous):

Please help me with few Acid Base questions!

OpenStudy (anonymous):

OpenStudy (anonymous):

in the image i understand NR9 , but not 27, 28 and NR 10 beacuse I am not sure how to make the eqaution from looking at the question

OpenStudy (caozeyuan):

let HA be an acid and A- be the conjugate base after dissociation and assume the solvent is water

OpenStudy (caozeyuan):

therefore we have the following equation\[HA \rightarrow A ^{-}+H _{3}O ^{+}\]

OpenStudy (caozeyuan):

Now, Ka is just the equilibrium constant of this equation

OpenStudy (caozeyuan):

understood?

OpenStudy (anonymous):

not really

OpenStudy (caozeyuan):

well, acid dissociates in water to form the conjugate base and hydronium according to the equation above. I hope your teacher told you what is the conjugate base of an acid. If not, the easiest way to think of it is to rip off the proton and whatever left is the cb

OpenStudy (anonymous):

then will the eqaution look like Nan3 + h20= H30 + ??? somthng like this?

OpenStudy (caozeyuan):

We know that any equilibrium has a constant K which is a ration of forward versus reverse reaction.\[aA+bB \rightarrow cC+dD\]\[\frac{ A^{a} B^{b}}{ C ^{c} D ^{d}}\]

OpenStudy (caozeyuan):

you should use HN3, not NaN3 because NAN3 is not acid so it cannot protinate water

OpenStudy (caozeyuan):

so we have HN#+H2O=H3O+ + N3-

OpenStudy (caozeyuan):

H2O is left out in the Ka expression because solvent is not part of the equilibrium expression

OpenStudy (anonymous):

then why does it give NaOH concentration in NR 10?

OpenStudy (caozeyuan):

Because NaOH is used to neutralize HN3

OpenStudy (anonymous):

damn this is just confusing then how would u slow it when Naoh is not in the equation we made

OpenStudy (caozeyuan):

Lets get Q27 out first, ok?

OpenStudy (anonymous):

okey

OpenStudy (anonymous):

I can do that one looking at the eqatuion so I am fine with that question

OpenStudy (caozeyuan):

So Ka is the acid dissociation constant, which is a special case of equilibrium constant, did your teach laugh you these terms?

OpenStudy (anonymous):

yes

OpenStudy (caozeyuan):

OK, so you should know product over reactants, constants are powers, stuff like that, right?

OpenStudy (anonymous):

yes easy

OpenStudy (caozeyuan):

Great, so what is the dissociate reaction of HN3 with H2O?

OpenStudy (anonymous):

what do u mean

OpenStudy (caozeyuan):

\[HN _{3}+H2O \rightarrow H3O ^{+}+N _{3}^{-}\]

OpenStudy (caozeyuan):

I mean this equation

OpenStudy (anonymous):

ok what do u want me to do

OpenStudy (caozeyuan):

write the expression for Ka of this reaction

OpenStudy (anonymous):

I would say the answer is B

OpenStudy (anonymous):

since liquids dont coiunt

OpenStudy (caozeyuan):

Fantastic! 27 solved! You still have problem with 28?

OpenStudy (anonymous):

yes

OpenStudy (anonymous):

wait first of all

OpenStudy (anonymous):

I have to remeber that theory u told me right when making thses eqautions

OpenStudy (caozeyuan):

you just did it right

OpenStudy (anonymous):

no i am talking about the ionic eqaution

OpenStudy (caozeyuan):

Well acid donates proton to water to form hydronium ion and conjugate base

OpenStudy (caozeyuan):

makes sense?

OpenStudy (anonymous):

alright lets move on

OpenStudy (caozeyuan):

In this case, HN3 is acid, H2O is water, H3O+ is hydronium and N3- is conjugate base

OpenStudy (caozeyuan):

OK, 28 is simple. remember this: if the numeric value for Ka is less than 1, bottom is larger, if it is bigger than i top is larger

OpenStudy (caozeyuan):

there is no chemistry, only math

OpenStudy (caozeyuan):

it's like say 5/7 is less than 1, why? because bottom is large. 7/5 is larger than 1 because top is large

OpenStudy (anonymous):

answer is A?

OpenStudy (caozeyuan):

Back to chem, bottom is reactant, top is product, so which side has higher concentration?

OpenStudy (caozeyuan):

let's not jump too fast

OpenStudy (anonymous):

why is there no sigh of H30

OpenStudy (caozeyuan):

is Ka larger or smaller than 1?

OpenStudy (anonymous):

yes

OpenStudy (caozeyuan):

Ka is smaller than 1, right?

OpenStudy (anonymous):

yes

OpenStudy (caozeyuan):

so which side has higher concentration?

OpenStudy (anonymous):

bottn is larger

OpenStudy (anonymous):

hold up its B!

OpenStudy (caozeyuan):

Great!

OpenStudy (caozeyuan):

Now, onto calculation

OpenStudy (anonymous):

i understand nr9 , nr10 is confusing

OpenStudy (caozeyuan):

lets start with basics

OpenStudy (caozeyuan):

how many moles of Hydronium can 1 mole of HN3 produce?

OpenStudy (caozeyuan):

solvent is 1L of H2O of cuz

OpenStudy (anonymous):

okay

OpenStudy (caozeyuan):

how many moles of Hydronium can 1 mole of HN3 produce?

OpenStudy (anonymous):

not sure.....

OpenStudy (caozeyuan):

\[K _{a}=x^2,x=\left[ H3O+ \right]\]

OpenStudy (anonymous):

o yea i know that eqaution wait r u trying to do nr9?

OpenStudy (caozeyuan):

No, but we need this info to do 10

OpenStudy (anonymous):

oh

OpenStudy (anonymous):

k i already foinf the ph its 2.64

OpenStudy (caozeyuan):

so we have 10^-2.64 mole of H3O+, right?

OpenStudy (anonymous):

yes

OpenStudy (caozeyuan):

how many mole of HN3 is 2.2kg?

OpenStudy (anonymous):

51.15089514

OpenStudy (caozeyuan):

Great, but three digit is enough for your question

OpenStudy (anonymous):

ok

OpenStudy (anonymous):

why did they give conc for naoh?

OpenStudy (caozeyuan):

If we have n moles of HN3, we can produce N*10^-2.64 mole of H3O+

OpenStudy (caozeyuan):

which means we need this many mole of NaOH to completely neutralize

OpenStudy (caozeyuan):

molar concentration=mole/liter, right?

OpenStudy (anonymous):

yes

OpenStudy (caozeyuan):

we have two of three, can you solve the third?

OpenStudy (caozeyuan):

that's why we need conc of NaOh

OpenStudy (anonymous):

we already have the conce its 6.00 mol/l given in the question

OpenStudy (caozeyuan):

Yes, and we know the mole, right?

OpenStudy (anonymous):

8.585

OpenStudy (anonymous):

wait i am confued ususaly we have an eqaution when we dod these kind of question

OpenStudy (caozeyuan):

Now, can you solve for the liter

OpenStudy (anonymous):

that is in liter

OpenStudy (caozeyuan):

I am not sure what are you confused about

OpenStudy (anonymous):

where is the eqaution?

OpenStudy (anonymous):

like Naoh+hn3?----?

OpenStudy (caozeyuan):

NO!, you don't need that

OpenStudy (caozeyuan):

a molar is 1mole over 1 liter

OpenStudy (anonymous):

becuz this is like a chem grade 11 question

OpenStudy (caozeyuan):

now you know how many moles you have, and how many molar you have

OpenStudy (anonymous):

we uusaly do some kind of eqautoon to get the moles right

OpenStudy (caozeyuan):

can you find the amount of liter

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