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Chemistry 10 Online
OpenStudy (priyar):

how is change in internal energy zero in an isothermal reversible expansion of gas?

OpenStudy (priyar):

@JFraser @samigupta8 @imqwerty

OpenStudy (priyar):

also why is the internal energy dependent on temperature..?

OpenStudy (priyar):

@baru @ParthKohli @rvc @mayankdevnani

OpenStudy (priyar):

@Abhisar @iGreen

OpenStudy (samigupta8):

Bcz ∆U=nCv∆T

OpenStudy (priyar):

but this is only when work is zero right..?

OpenStudy (samigupta8):

Nope ..it"zz a general equation for change in internal energy

OpenStudy (priyar):

but.. delta U = q +W and q=Cdelta T right?

OpenStudy (samigupta8):

Yup. ..bt don't confuse C vid Cv

OpenStudy (priyar):

oh..what is the diff.. i forgot..

OpenStudy (samigupta8):

C is molar heat capCity .... N Cv is heat capacity at const.volume

OpenStudy (priyar):

how do we derive this eq..?

OpenStudy (samigupta8):

I don't know d derivation

OpenStudy (samigupta8):

Sorry. ...

OpenStudy (priyar):

oh..its ok..but does this hold true always..

OpenStudy (priyar):

@samigupta8 ?

OpenStudy (priyar):

?

OpenStudy (samigupta8):

Yess it is d general formula

OpenStudy (samigupta8):

It hold true in oll cases

OpenStudy (priyar):

ok..i think i forgot.. but isn't Cv a special case of C?

OpenStudy (samigupta8):

Yes i told u at constant volune

OpenStudy (priyar):

so..i was right work done is zero here coz const. volume..we must have used that to derive this..thanks..

OpenStudy (priyar):

hey i have a small doubt..

OpenStudy (samigupta8):

Yes

OpenStudy (samigupta8):

Wt is d doubt

OpenStudy (priyar):

what is \[\Delta n g\] for formation of CO? is it 1/2 or 1 ?

OpenStudy (priyar):

it seems both r correct..?

OpenStudy (samigupta8):

U need to describe d equation for dat

OpenStudy (samigupta8):

It can be anything ...bcz it depnds on stoichiometric coefficients present in front of d reactants n producrs

OpenStudy (priyar):

no..it was asked just like that..i mean we needed to use this value in the problem..and both are given in the options..(i mean both ways....)

OpenStudy (priyar):

what to do? which to choose?

OpenStudy (priyar):

@Rushwr @rvc can u help here?

OpenStudy (priyar):

what is Δng for formation of CO? is it 1/2 or 1 ?

OpenStudy (priyar):

\[\Delta n _{g}\] = no of moles of gaseous products - reactants

OpenStudy (priyar):

i am asking what will be this quantity's values for the formation of carbon monoxide..we must write the eq balance and then find out... but it seems to me that 2 values are correct..thats why i m asking...

OpenStudy (priyar):

thats not my Q... i have asked another Q abv

OpenStudy (priyar):

Δng = no of moles of gaseous products - reactants i am asking what will be this quantity's values for the formation of carbon monoxide..we must write the eq balance and then find out... but it seems to me that 2 values are correct..thats why i m asking...

OpenStudy (priyar):

ok i will..wait..

OpenStudy (abhisar):

Remember this is only true in case of an Ideal gas

OpenStudy (abhisar):

Change in internal energy for an ideal gas depends only upon temperature and hence for an Isothermal change change in internal energy is 0 for an ideal gas.

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