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Chemistry 19 Online
OpenStudy (jessica2499):

How does deltaG° relate to K for a reaction? A. When deltaG° > 0, K < 1 and products are favored. B. When deltaG° < 0, K > 1 and products are favored. C. When deltaG° < 0, K < 1 and reactants are favored. D. When deltaG° > 0, K > 1 and reactants are favored.

OpenStudy (jfraser):

There's an equation that links \(\Delta G\) and \(K\), have you got it?

OpenStudy (jessica2499):

No? can you give it to me?

OpenStudy (jfraser):

\[\Delta G = -R*T*ln(K_{EQ})\]

OpenStudy (jessica2499):

Is the answer c?

OpenStudy (jessica2499):

Also, can someone tell me what it means to bump a question?

OpenStudy (jessica2499):

And to close a question?

OpenStudy (jfraser):

it's not C. You need to know what a negative \(\Delta G\) \(means\) for a reaction, and how to move the math around so that if you know that \(\Delta G\) is negative, what the value of \(K\) will be. A negative \(\Delta G\) means that a reaction is spontaneous, and moves towards products. So that eliminates 2 options right away, doesn't it?

OpenStudy (jessica2499):

does it eliminate b too?

OpenStudy (jfraser):

it does not eliminate B. You need to decide whether the first statement is true, about when \(\Delta G\) is negative, what that means for \(K\). I'll use choice A as an example

OpenStudy (jfraser):

By rearranging the equation to solve for \(K\), I get \[K = e^{\frac{-\Delta G}{RT}}\] If \(\Delta G\) is positive, as in choice A, what does that \(guarantee\) about the sign of \(K\)? It guarantees that it is going to be negative. So far that statement is algebraically correct. The SECOND part of the problem asks what \(direction\) the reaction favors under those conditions. Since we've made \(\Delta G\) positive, that means the reaction WON'T move forward, and the products \(aren't\) favored. Choice A is incorrect

OpenStudy (jessica2499):

so therefore it is either b or d?

OpenStudy (jessica2499):

i think b...

OpenStudy (jfraser):

it is B

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