1. A flask contains 4.00 g of solid sodium hydroxide. Some water is added to the flask to dissolve the sodium hydroxide, and enough water is added to fill the flask to a volume of 50.0 mL. What volume of 1.00 M HCl is needed to neutralize the sodium hydroxide? A. 50.0 mL B. 100.0 mL C. 200.0 mL 2. A beaker contains 100.0 mL of a 0.100 M solution of sulfuric acid. When 100.0 mL water is added to this solution, what is the concentration of the diluted sulfuric acid? A. 0.0250 M B. 0.0500 M C. 0.200 M 3. How many moles of NaOH are required to react completely with 1.00 mole of nitric acid? A. 1.00 mol B. 0.500 mol C. 2.000 mol Please explain. Thank you!
Sorry I do not know how to explain this. However I found that @Kevin, is great at this stuff. He will be online soon, so stay online. yw
@Kevin, make sure you explain it to this guy.
I could do this, but it's pretty late in my part of the world and with my schedule, so I can get on this first thing in the morning if no one else answers, seem ok @KJ4UTS?
@SapphireMoon no problem, I appreciate any help you can give me. This is a new unit for me and im having some difficulty understanding it. Thanks again :)
Answer 1 :- concentration of NaOH after dissolution of 50 ml of water in it = \[\text{Molarity }= \frac{\text{no. of moles of solute} }{\text{volume of solution in liters}}\] number of moles of NaOH= \(\Large\frac{4}{40}\) volume of solution in liters = \(\Large \frac{50}{1000}\) L concentration of NaOH = \(\Large \frac{4/40}{50/1000}\) M Remember the fact that during Neutralization reaction Milli-equivalents of acid = Milliequivalents of base (number of milliequivalents = Molarity * n-factor * volume of solution in milliliters)
n-factor for HCl =1 n-factor for NaOH =1 Let the volume of HCl required for neutralization be 'V' ml Milliequivalents of HCl = Milliequivalents of NaOH 1M * 1 * V= \(\Large \frac{4/40}{50/1000}\) * 1 * 50 .......(1) solve equation (1) yo get 'V'. remember u will gt volume in milliliters
Answer :- 2 During dilution number of moles of the solute do not alter so \[M_1 V_1=M_2 V_2\] \(M_1\) = initial concentration \(M_2\)=final concentration \(V_1\)=Initial volume of solution \(V_2\)=final volume of solution can u apply this rule now to find answer for question 2 ?
Answer :- As i told u earlier that during neutralization reaction (Milli-equivalents of acid = Milliequivalents of base) (milliequivalent of a compound = no. of moles of that substance * n-factor) milliequivalents of nitric acid = 1*1=1 (as both no. of moles & n-factor of \(HNO_3\) are 1) Let the number of moles of NaOH required for neutralization of \(HNO_3\) be 'n'. milliequivalents of NaOH = n*1 (as no. of moles of NaOH is n & n-factor is 1) Therefore, milliequivalents of nitric acid=milliequivalents of NaOH 1*1=n*1
1) M = gr/Mr x 1000/p M = 4/40 x 1000/50 M = 2 M1 x V1 = M2 x V2 2 x 50 = 1 x V2 V2 = 100 2) M1 x V2 = M2 x V2 (just like the question on number 1) 3) HNO3 + NaOH -> NaNO3 + H2O HNO3 -> H^+ + NO3^- -> valency of H+ = 1 NaOH -> Na^+ + OH^- -> valency of OH^- = 1 M1 x V1 x valency = M2 x V2 x valency mole1 x valency = mole2 x valency 1 x 1 = mole2 x 1
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