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lisa:

why is 6-decene not possible

Vocaloid:

start by drawing decane (10 saturated carbon atoms in a chain)

Vocaloid:

then put a double-bond on carbon 6

Vocaloid:

from the structure, determine it's proper name under iupac rules (the lowest number must be given to the double bond)

lisa:

what is the lowest number?

lisa:

so carbon 1 is the lowest number?

Vocaloid:

|dw:1507171302299:dw|

lisa:

sorry, i still don't get it

Vocaloid:

you can start numbering from the left side or the right side which direction gives the double bond the lowest number?

lisa:

but how would you know by just knowing the formula?

Vocaloid:

how would I know what?

lisa:

the direction?

Vocaloid:

whichever direction gives the alkene bond the lowest number is the correct direction

Vocaloid:

try both directions. start numbering the carbons from the left then try numbering the carbons from the right which one gives you the lowest number for the alkene bond?

lisa:

|dw:1507173135992:dw|

lisa:

what do i do next?

Vocaloid:

\(\color{#0cbb34}{\text{Originally Posted by}}\) @Vocaloid then put a double-bond on carbon 6 \(\color{#0cbb34}{\text{End of Quote}}\)

lisa:

|dw:1507173267875:dw|

Vocaloid:

that's carbon 5

lisa:

|dw:1507173311174:dw|

Vocaloid:

good now try numbering the compound from the left then try from the right then see which direction gives the lowest number for the double bond

lisa:

|dw:1507173390285:dw|

Vocaloid:

good so the compound's actual name is 4-decene

Vocaloid:

(6-decene is not a proper name under iupac)

lisa:

some of the website said is 2-decene?

Vocaloid:

no idea how they got 2-decene

lisa:

the only possibility is 4 ?

Vocaloid:

yes

lisa:

what does it mean "dec-6-ene"

Vocaloid:

dec-6-ene is just another way to write 6-decene

Vocaloid:

sometimes the double-bond locant is written after the latin prefix

lisa:

so 6-decene is not possible

Vocaloid:

no it is not possible

lisa:

but why do i draw the double in the #6 carbon

lisa:

*bond

Vocaloid:

the original name is incorrect but we can use it to figure out the correct name

Vocaloid:

6-decene means a double bond on the 6th carbon

Vocaloid:

(from the wrong direction)

lisa:

the right location is at #4 carbon?

Vocaloid:

it's the 6th from the wrong direction and the 4th from the right direction

lisa:

???

Vocaloid:

let me try to explain

lisa:

ok

lisa:

thx

Vocaloid:

normally we would give iupac names to give the double bond the lowest number

Vocaloid:

imagine a bad chemist found a compound, named it from the wrong direction, and told you there was a double bond on carbon 6

Vocaloid:

giving you the name 6-decene

Vocaloid:

now, a good chemist will use that name to draw the compound. he draws it, and realizes that he needs to number it from the other end to give the proper iupac name

Vocaloid:

making the real name 4-decene

Vocaloid:

the "6th carbon" is part of the bad chemist's misinformation

Vocaloid:

but we can use that misinformation to get the real name

Vocaloid:

|dw:1507172559511:dw|

lisa:

ok

lisa:

got it now

lisa:

can i ask you another question?

Vocaloid:

sure

lisa:

why butene have 2 ways to draw?

lisa:

that's ok

lisa:

the question is how many ways can you write butene?

lisa:

and the answer is 1,2-butene but idk why is that answer

Vocaloid:

oh I think they just want these two structures

Vocaloid:

1-butene: H3C-CH2-CH=CH2 2-butene: H3C-CH=CH-CH3 both are considered butene but one has the double bond shifted over to the 2-carbon position

lisa:

yeah, but how would you know that there are 2 structures?

Vocaloid:

but- implies 4 carbons -ene implies one double bond (otherwise it would be butadiene)

Vocaloid:

1-butene and 2-butene are both classified as butene

Vocaloid:

so one of them has the double bond in the end and the other one has the double bond in the middle

Vocaloid:

you would just have to use some intuition + sketching out possible structures

lisa:

how come it can't be 3-butene?

Vocaloid:

lowest number rule

lisa:

it have to start from the left

Vocaloid:

no it doesn't it starts from whichever direction gives the lowest number

Vocaloid:

1-butene: H3C-CH2-CH=CH2 2-butene: H3C-CH=CH-CH3 "3-butene:" H3C=CH-CH-CH3 notice how "3-butene" is just 1-butene rotated around

lisa:

yes

lisa:

omg, i finally got it

Vocaloid:

since 1-butene has a lower number, then "3-butene" gets renamed as 1-butene

Vocaloid:

good

lisa:

thank you so much

lisa:

Can I ask for help in the future?

Vocaloid:

sure

lisa:

thx, good night!!!!!

Vocaloid:

Moved to Chemistry

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